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Synthesis and Structures of the Ligands 1-Methylimidazol-2-yl(pyridin-2-yl)-methanone {(py)(mim)CO} and 1-Benzylimidazol-2-yl(1-phenylaldimine)(PhN=CHbim) as their Tetracarbonylmolybdenum(0) Complexes[Mo(CO)4(L2-N,N')]

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Batten, MP and Canty, AJ and Cavell, KJ and Skelton, BW and White, AH (2006) Synthesis and Structures of the Ligands 1-Methylimidazol-2-yl(pyridin-2-yl)-methanone {(py)(mim)CO} and 1-Benzylimidazol-2-yl(1-phenylaldimine)(PhN=CHbim) as their Tetracarbonylmolybdenum(0) Complexes[Mo(CO)4(L2-N,N')]. Zeitschrift fur Anorganische und Allgemein Chemie, 632 (5). pp. 876-878. ISSN 0044-2313

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Abstract

The complexes [Mo(CO)4(L2-N,N')] [L2 = 1-methylimidazol- 2-yl(pyridin-2-yl)methanone and 1-benzylimidazol-2-yl(1- phenylaldimine)] have been synthesized from hexacarbonylmolybdenum(0) in order to define the coordination characteristics of the bidentate nitrogen-donor ligands; the complexes exhibit distorted octahedral coordination for molybdenum(0) and cis-bidentate ligand configurations.

Item Type: Article
Keywords: Molybdenum; Carbonyl; Imidazole; Crystal structure
Journal or Publication Title: Zeitschrift fur Anorganische und Allgemein Chemie
Page Range: pp. 876-878
ISSN: 0044-2313
Identification Number - DOI: 10.1002/zaac.200500531
Additional Information: "Submitted to/accepted for publication in (Zeitschrift fur Anorganische und Allgemein Chemie) (2006) WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim",
Date Deposited: 02 Jan 2008 01:18
Last Modified: 18 Nov 2014 03:26
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