Synthesis and Structures of the Ligands 1-Methylimidazol-2-yl(pyridin-2-yl)-methanone {(py)(mim)CO} and 1-Benzylimidazol-2-yl(1-phenylaldimine)(PhN=CHbim) as their Tetracarbonylmolybdenum(0) Complexes[Mo(CO)4(L2-N,N')]

Batten, MP and Canty, AJ and Cavell, KJ and Skelton, BW and White, AH (2006) Synthesis and Structures of the Ligands 1-Methylimidazol-2-yl(pyridin-2-yl)-methanone {(py)(mim)CO} and 1-Benzylimidazol-2-yl(1-phenylaldimine)(PhN=CHbim) as their Tetracarbonylmolybdenum(0) Complexes[Mo(CO)4(L2-N,N')]. Zeitschrift fur Anorganische und Allgemein Chemie, 632 (5). pp. 876-878. ISSN 0044-2313

PDF - Full text restricted - Requires a PDF viewer
88Kb

Official URL: http://dx.doi.org/10.1002/zaac.200500531

Abstract

The complexes [Mo(CO)4(L2-N,N')] [L2 = 1-methylimidazol- 2-yl(pyridin-2-yl)methanone and 1-benzylimidazol-2-yl(1- phenylaldimine)] have been synthesized from hexacarbonylmolybdenum(0) in order to define the coordination characteristics of the bidentate nitrogen-donor ligands; the complexes exhibit distorted octahedral coordination for molybdenum(0) and cis-bidentate ligand configurations.

Item Type:	Article
Additional Information:	"Submitted to/accepted for publication in (Zeitschrift fur Anorganische und Allgemein Chemie) (2006) WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim",
Keywords:	Molybdenum; Carbonyl; Imidazole; Crystal structure
ID Code:	2788
Deposited By:	Prof Allan J Canty
Deposited On:	02 Jan 2008 12:18
Last Modified:	18 Jul 2008 20:26
ePrint Statistics:	View statistics for this ePrint

Repository Staff Only: item control page