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Convenient synthetic routes to MePd(II), Me2Pd(II), and Me3Pd(IV) complexes. The crystal structure of the MePd(II) complex [MePd(2,2’-bipyridyl)(y-picoline)]BF4

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Byers, PK and Canty, AJ and Skelton, BW and White, AH (1987) Convenient synthetic routes to MePd(II), Me2Pd(II), and Me3Pd(IV) complexes. The crystal structure of the MePd(II) complex [MePd(2,2’-bipyridyl)(y-picoline)]BF4. Journal of Organometallic Chemistry, 336 (3). C55-C60. ISSN 0022-328X

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Abstract

The pyridazine complex [Me2Pd(pyd)]n, stable as a solid on storage at ca. -20°C and obtained on reaction of trans-PdCl2(SMe2)2 with methyllithium and pyridazine at low temperature, is an excellent precursor for the synthesis of Me2Pd(II) and Me3Pd(IV) complexes under mild conditions, in particular for ligands sensitive to MeLi. Similarly, [MePd(SMe2)(mu-I)]2 is a suitable precursor for the synthesis of neutral and cationic MePd(II) complexes, including [MePd(2,2’-bipyridyl)(gamma-picoline)]BF4, which has been characterized by X-ray crystallography.

Item Type: Article
Journal or Publication Title: Journal of Organometallic Chemistry
Page Range: C55-C60
ISSN: 0022-328X
Identification Number - DOI: 10.1016/j.jorganchem.2003.12.010
Additional Information: The definitive version is available at http://www.sciencedirect.com/
Date Deposited: 16 Mar 2008 21:35
Last Modified: 18 Nov 2014 03:26
URI: http://eprints.utas.edu.au/id/eprint/2814
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