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Organomercury Compounds XI. Some Coordination Derivatives of Bispentafluorophenylmercury

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Canty, AJ and Deacon, GB (1971) Organomercury Compounds XI. Some Coordination Derivatives of Bispentafluorophenylmercury. Australian Journal of Chemistry, 24 (3). pp. 489-499. ISSN 0004-9425

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Abstract

The oomplexes (C6F5)2HgL (L = 4,4'-dimethyl-2,2'-bipyridyl, 2,2'-biquinolyl, 2,2':6',2"-terpyridyl, 2,4,7,9-tetramethyl-1,lO-phenanthroline, ethylenediamine, o-phenylenediamine, diphenylamine, pyridine, 4-cyanopyridine, triphenylphosphine, triphenylphosphine oxide, or 1,2-bisdiphenylarsinoethane), (C6F5)HgL2 (L = di-2-pyridylamine), and [(C6F5)2Hg]L (L = bisdiphenylphosphinomethane or bisdiphenylarsinomethane) have been prepared, and their constitution, solution stabilities, and structures studied, together with those of the known complexes (C6F5)2HgL (L = 2,2'- bipyridyl, 1,lO-phenanthroline, or 1,2-bisdiphenylphosphinoethane). Coordination of triphenylarsine oxide to bispentafluorophenylmercury in solution has also been detected, but the complex could not be isolated.

Item Type: Article
Journal or Publication Title: Australian Journal of Chemistry
Page Range: pp. 489-499
ISSN: 0004-9425
Identification Number - DOI: 10.1071/CH9710489
Date Deposited: 10 Jan 2008 22:50
Last Modified: 18 Nov 2014 03:26
URI: http://eprints.utas.edu.au/id/eprint/2821
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