Library Open Repository

Metal-Sulphur Stretching Frequencies and Structures of Complexes of Zinc, Cadmium, and Mercury with Thiols

Downloads

Downloads per month over past year

Canty, AJ and Kishimoto, R and Deacon, GB and Farquharson, GJ (1976) Metal-Sulphur Stretching Frequencies and Structures of Complexes of Zinc, Cadmium, and Mercury with Thiols. Inorganica Chimica Acta, 20. pp. 161-166. ISSN 0020-1693

[img] PDF
ICA1976_2C_161.pdf | Request a copy
Full text restricted
Available under University of Tasmania Standard License.

Abstract

Assignments of vas(SMS) and vsym(SMS) for the complexes M(SR)2 (M = Zn, Cd, Hg; R = Et, But) and Hg(SMe)2 from infrared and Raman spectroscopy are reported. Comparison of frequencies for the complex Hg(SBut)2 containing four-coordinate mercury with those of Hg(SR)2 (R = Me, Et) containing two-coordinate mercury permits assignment of a polymeric structure with linear coordination for the 1:I complex of Hg(II) with the antidote for mercury poisoning 2,3-dimercaptopropanol (British anti-Lewisite).

Item Type: Article
Journal or Publication Title: Inorganica Chimica Acta
Page Range: pp. 161-166
ISSN: 0020-1693
Identification Number - DOI: 10.1016/S0020-1693(00)94110-0
Additional Information: The definitive version is available at http://www.sciencedirect.com
Date Deposited: 11 Jan 2008 00:49
Last Modified: 18 Nov 2014 03:26
URI: http://eprints.utas.edu.au/id/eprint/2827
Item Statistics: View statistics for this item

Repository Staff Only (login required)

Item Control Page Item Control Page