File(s) under permanent embargo
Pi-Bonded alkene and arene complexes of silver(I): an electrospray mass spectrometric study
journal contribution
posted on 2023-05-25, 23:17 authored by Canty, AJ, Colton, RElectrospray mass spectra have been observed for a number of alkene and arene complexes of Ag(1) formed by the interaction of AgN03 and the organometallic ligand in water/methanol solution. The ES mass spectra show that almost all the alkene and arene ligands in stoichiometric excess form labile 1:2 cationic complexes with Ag(I) which are easily decomposed by collisional activation to the 1:l species. However, with a deficiency of organic ligand polymeric species are observed. The cation [Ag(cod)2]+ (cod = 1,5-cyclooctadiene) was reacted with a variety of other potential ligands, such as PPh3, AsPh3, PhSCHSPh etc. In most cases, mixed complexes [Ag(cod)(ligand)]+ were observed, and excess ligand usually produced [Ag(ligand)2]+.
History
Publication title
Inorganica Chimica ActaVolume
220Article number
1-2'Number
1-2'Pagination
99-105ISSN
0020-1693Publication status
- Published
Rights statement
The definitive version is available at http://www.sciencedirect.comRepository Status
- Restricted
Usage metrics
Categories
No categories selectedKeywords
Licence
Exports
RefWorks
BibTeX
Ref. manager
Endnote
DataCite
NLM
DC