Due to routine maintenance, access to the Library Open Repository will be interrupted on the morning of Friday 12th February.
We apologise for any inconvenience.

Library Open Repository

Metallation of Tris(1-pyrazolyl)methane by Dimethylplatinum(II)

Downloads

Downloads per month over past year

Canty, AJ and Minchin, NJ (1982) Metallation of Tris(1-pyrazolyl)methane by Dimethylplatinum(II). Journal of Organometallic Chemistry, 226 (1). C14-C16. ISSN 0022-328X

[img] PDF
JOMC1982_2C_C14...pdf | Request a copy
Full text restricted
Available under University of Tasmania Standard License.

Abstract

Tris(l-pyrazolyl)methane (HCpz3) reacts with Pt(CH3)2(COD) to form Pt(CH3)2(HCpz3), and when this complex is heated in pyridine metallation of the pyrazole ring at C(5) occurs to form Pt(CH3)(HCpz2(pzH-1))(py). A triphenylphosphine derivative, Pt(CH3)(HCpz2(PzH-1)(PPh3)2, when slowly heated to 185°C forms Pt(HCpz2(pzH-1))(C6H4PPh2); this complex has both the nitrogen and phosphorus donor ligands metallated to form six and four membered rings, respectively.

Item Type: Article
Journal or Publication Title: Journal of Organometallic Chemistry
Page Range: C14-C16
ISSN: 0022-328X
Identification Number - DOI: 10.1016/S0022-328X(00)83400-2
Additional Information: The definitive version is available at http://www.sciencedirect.com
Date Deposited: 15 Jan 2008 04:32
Last Modified: 18 Nov 2014 03:27
Item Statistics: View statistics for this item

Repository Staff Only (login required)

Item Control Page Item Control Page