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Organopalladium(IV) complexes containing phosphine ligands, and the structure of the platinum(IV) complex [PtMe3(bpy)(PPh3)][O3SCF3] (bpy = 2,2'-bipyridine)

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Bayler, A and Canty, AJ and Skelton, BW and White, AH (2000) Organopalladium(IV) complexes containing phosphine ligands, and the structure of the platinum(IV) complex [PtMe3(bpy)(PPh3)][O3SCF3] (bpy = 2,2'-bipyridine). Journal of Organometallic Chemistry, 595 (2). pp. 296-299. ISSN 0022-328X

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Abstract

Solutions containing unstable organopalladium(IV) complexes of phosphines, [PdMe3(bpy)(L)]+ (L = PMePh2, PMe2Ph, PPh3), are generated on reaction of PdIMe3(bpy) with the phosphines in dichloromethane-d2. The complex [PdMe3(bpy)(PPh3)]+ may also be formed quantitatively on the reaction of PdMe2(bpy) with methyl triflate and triphenylphosphine in acetone-d6. A solution of the platinum(IV) analogue [PtMe3(bpy)(PPh3)][O3SCF3] is formed following a similar procedure and isolated as crystals on reaction of PtIMe3(bpy) with silver triflate followed by PPh3. An X-ray structure determination of the platinum(IV) complex shows the fac-PtMe3 configuration for octahedral [PtMe3(bpy)(PPh3)]+, and supports the assignment of identical structures for the unstable palladium(IV) complexes from comparison of 1H- and 13P-NMR spectra of palladium(IV) and platinum(IV) complexes.

Item Type: Article
Journal or Publication Title: Journal of Organometallic Chemistry
Page Range: pp. 296-299
ISSN: 0022-328X
Identification Number - DOI: 10.1016/S0022-328X(99)00626-9
Additional Information: The original publication is available at www.springerlink.com
Date Deposited: 17 Jan 2008 02:16
Last Modified: 18 Nov 2014 03:27
URI: http://eprints.utas.edu.au/id/eprint/2890
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