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The Oxidative Addition of Iodomethane to [PdMe2(bpy)] and the X-Ray Structure of the Organopalladium(IV) Product fac-[PdMe3(bpy)l] (bpy = 2,2'-bipyridyl)
Byers, PK and Canty, AJ and Skelton, BW and White, AH (1986) The Oxidative Addition of Iodomethane to [PdMe2(bpy)] and the X-Ray Structure of the Organopalladium(IV) Product fac-[PdMe3(bpy)l] (bpy = 2,2'-bipyridyl). Journal of the Chemical Society, Chemical Communications, 23. pp. 1722-1724. ISSN 1359-7345
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Oxidative addition of iodomethane to dimethyl(2,2'-bipyridyl)palladium(II) in acetone has resulted in isolation of the first hydrocarbylpalladium(IV) complex, fac-trimethyl(2,2'-bipyridyl)iodopalladium(IV); the complex has been structurally characterized, and reductively eliminates ethane in solution to form methyl(2,2'-bipyridy1)iodopalladium(II).
|Journal or Publication Title:||Journal of the Chemical Society, Chemical Communications|
|Page Range:||pp. 1722-1724|
|Identification Number - DOI:||10.1039/C39860001722|
|Date Deposited:||29 Jan 2008 00:51|
|Last Modified:||18 Nov 2014 03:27|
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