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An electrospray mass spectrometric study of methylmercury(II) nitrogen base derivatives and their ligand exchange reactions

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Canty, AJ and Colton, R (1994) An electrospray mass spectrometric study of methylmercury(II) nitrogen base derivatives and their ligand exchange reactions. Inorganica Chimica Acta, 215. pp. 179-184. ISSN 0020-1693

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Abstract

Electrospray mass spectra have been observed for solutions of a number of methylmercury(II) complexes of the type [MeHgL]+ (L= neutral nitrogen base, e.g. N-methylpyrazoles, bis(pyridin-2-yl)methane, etc.) and PhHg(II) complexes of creatinine and in all cases the intact ion was observed. Electrospray mass spectrometry is a convenient technique with which to investigate ligand exchange reactions in solution, and the reactlons of the N-methylpyrazole complex [MeHg(C4H6N2)]+ have been studied with a variety of reagents including other nitrogen bases, phosphines and phosphine sulfides and selenides.

Item Type: Article
Journal or Publication Title: Inorganica Chimica Acta
Page Range: pp. 179-184
ISSN: 0020-1693
Additional Information: The definitive version is available at http://www.sciencedirect.com
Date Deposited: 30 Jan 2008 01:44
Last Modified: 18 Nov 2014 03:27
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