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An electrospray mass spectrometric study of methylmercury(II) nitrogen base derivatives and their ligand exchange reactions
Canty, AJ and Colton, R (1994) An electrospray mass spectrometric study of methylmercury(II) nitrogen base derivatives and their ligand exchange reactions. Inorganica Chimica Acta, 215. pp. 179-184. ISSN 0020-1693
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Electrospray mass spectra have been observed for solutions of a number of methylmercury(II) complexes of the type [MeHgL]+ (L= neutral nitrogen base, e.g. N-methylpyrazoles, bis(pyridin-2-yl)methane, etc.) and PhHg(II) complexes of creatinine and in all cases the intact ion was observed. Electrospray mass spectrometry is a convenient technique with which to investigate ligand exchange reactions in solution, and the reactlons of the N-methylpyrazole complex [MeHg(C4H6N2)]+ have been studied with a variety of reagents including other nitrogen bases, phosphines and phosphine sulfides and selenides.
|Journal or Publication Title:||Inorganica Chimica Acta|
|Page Range:||pp. 179-184|
|Additional Information:||The definitive version is available at http://www.sciencedirect.com|
|Date Deposited:||30 Jan 2008 01:44|
|Last Modified:||18 Nov 2014 03:27|
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