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Synthesis and Spectroscopic Studies of RSHg(II) Complexes, Including Complexes of ButSHgX (X = C1, Br) and RSHgO2CMe (R = Me, Et) with Pyridine
Canty, AJ and Kishimoto, R and Tyson, RK (1978) Synthesis and Spectroscopic Studies of RSHg(II) Complexes, Including Complexes of ButSHgX (X = C1, Br) and RSHgO2CMe (R = Me, Et) with Pyridine. Australian Journal of Chemistry, 31 (3). pp. 671-676. ISSN 0004-9425
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The complexes RSHgX (R = Et, But; X = C1, Br) may be prepared by reaction of the alkanethiol with HgX2 in ethanol, and the 2-methylpropane-2-thiolates crystallize from pyridine as (ButSHgC1)2C5H5N and ButSHgBr.C5H5N. The complexes RSHgO2CMe (R = Me, Et) may be prepared by reaction of mercuric acetate with Hg(SR)2 in water, and form crystalline RSHgO2CMe.C5H5N when dissolved in pyridine. Infrared and Raman spectra indicate coordination of pyridine in the pyridinates. Mercury-sulfur stretching vibrations of RSHg02CMe (R = Me, Et, Pr, Bu) are discussed.
|Journal or Publication Title:||Australian Journal of Chemistry|
|Page Range:||pp. 671-676|
|Identification Number - DOI:||10.1071/CH9780671|
|Date Deposited:||31 Jan 2008 21:35|
|Last Modified:||18 Nov 2014 03:27|
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