The Structure of [PdC12{(Py)2(PyH)CH-N',N"}][PdCl4]0.5.2H20 (Py = Pyridin-2-yl),a Complex with Protonated 2,2',2"-Methylidynetrispyridine as a Bidentate Ligand

Canty, AJ and Minchin, NJ and Skelton, BW and White, AH (1992) The Structure of [PdC12{(Py)2(PyH)CH-N',N"}][PdCl4]0.5.2H20 (Py = Pyridin-2-yl),a Complex with Protonated 2,2',2"-Methylidynetrispyridine as a Bidentate Ligand. Australian Journal of Chemistry, 45 (2). pp. 423-427. ISSN 0004-9425

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Abstract

Crystals of dichloro[2,2',2"-methylidynetris(pyridin)-1- ium- N',N"]palladium(II) hemi[tetrachloropalladate(II)] dihydrate are monoclinic, P21/c, a 8.558(5), b 15.516(7), c 16.153(5) a, beta 112.07(4), Z 4. The cations [PdCl2 {(Py)2(PyH)CH-N',N")]+ have square-planar geometry for palladium, with the ligand in a boat conformation and having an uncoordinated protonated pyridine group. The complex contains monoprotonated tris(pyridin-2-yl)methane as a bidentate ligand.

Item Type:	Article
ID Code:	2932
Deposited By:	Prof Allan J Canty
Deposited On:	01 Feb 2008 10:32
Last Modified:	18 Jul 2008 20:29
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