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Interaction of MeSHgO2CMe with Imidazole and Related Ligands
Canty, AJ and Tyson, RK (1978) Interaction of MeSHgO2CMe with Imidazole and Related Ligands. Inorganica Chimica Acta, 29. pp. 227-230. ISSN 0020-1693
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The complex methanethiolatomercury(II) acetate, MeSHgO2Me, reacts with imidazole (LH) in 1:l or 2:1 mol ratio in water at low pH to form a complex of stoichiometry (MeSHg)2(O2CMe)(L), but in the absence of acetic acid forms a new phase of bis(methanethiolato)mercury(II), Hg(SMe)2. Stirred suspensions of MeSHgO2CMe with imidazole or 2-methylimidazole in 1:l mol ratio in ethanol form (MeSHg)2(O2CMe)(L) and the 2-methylimidazole analogue. Solutions of MeSHgO2CMe or the new phase of Hg(SMe)2 in N-methylimidazole deposit crystals of the previously known phase of Hg(SMe)2.
|Journal or Publication Title:||Inorganica Chimica Acta|
|Page Range:||pp. 227-230|
|Identification Number - DOI:||10.1016/S0020-1693(00)89652-8|
|Additional Information:||The definitive version is available at http://www.sciencedirect.com/|
|Date Deposited:||22 Jan 2008 21:47|
|Last Modified:||18 Nov 2014 03:28|
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