Library Open Repository
Interaction of MeSHgO2CMe with Imidazole and Related Ligands
Canty, AJ and Tyson, RK (1978) Interaction of MeSHgO2CMe with Imidazole and Related Ligands. Inorganica Chimica Acta, 29. pp. 227-230. ISSN 0020-1693
ICA1978,_227.pdf | Request a copy
Full text restricted
Available under University of Tasmania Standard License.
The complex methanethiolatomercury(II) acetate, MeSHgO2Me, reacts with imidazole (LH) in 1:l or 2:1 mol ratio in water at low pH to form a complex of stoichiometry (MeSHg)2(O2CMe)(L), but in the absence of acetic acid forms a new phase of bis(methanethiolato)mercury(II), Hg(SMe)2. Stirred suspensions of MeSHgO2CMe with imidazole or 2-methylimidazole in 1:l mol ratio in ethanol form (MeSHg)2(O2CMe)(L) and the 2-methylimidazole analogue. Solutions of MeSHgO2CMe or the new phase of Hg(SMe)2 in N-methylimidazole deposit crystals of the previously known phase of Hg(SMe)2.
|Journal or Publication Title:||Inorganica Chimica Acta|
|Page Range:||pp. 227-230|
|Identification Number - DOI:||10.1016/S0020-1693(00)89652-8|
|Additional Information:||The definitive version is available at http://www.sciencedirect.com/|
|Date Deposited:||22 Jan 2008 21:47|
|Last Modified:||18 Nov 2014 03:28|
|Item Statistics:||View statistics for this item|
Actions (login required)
|Item Control Page|