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Interaction of MeSHgO2CMe with Imidazole and Related Ligands

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Canty, AJ and Tyson, RK (1978) Interaction of MeSHgO2CMe with Imidazole and Related Ligands. Inorganica Chimica Acta, 29. pp. 227-230. ISSN 0020-1693

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Abstract

The complex methanethiolatomercury(II) acetate, MeSHgO2Me, reacts with imidazole (LH) in 1:l or 2:1 mol ratio in water at low pH to form a complex of stoichiometry (MeSHg)2(O2CMe)(L), but in the absence of acetic acid forms a new phase of bis(methanethiolato)mercury(II), Hg(SMe)2. Stirred suspensions of MeSHgO2CMe with imidazole or 2-methylimidazole in 1:l mol ratio in ethanol form (MeSHg)2(O2CMe)(L) and the 2-methylimidazole analogue. Solutions of MeSHgO2CMe or the new phase of Hg(SMe)2 in N-methylimidazole deposit crystals of the previously known phase of Hg(SMe)2.

Item Type: Article
Journal or Publication Title: Inorganica Chimica Acta
Page Range: pp. 227-230
ISSN: 0020-1693
Identification Number - DOI: 10.1016/S0020-1693(00)89652-8
Additional Information: The definitive version is available at http://www.sciencedirect.com/
Date Deposited: 22 Jan 2008 21:47
Last Modified: 18 Nov 2014 03:28
URI: http://eprints.utas.edu.au/id/eprint/3006
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