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Weak Intramolecular Pi Coordination to Methylmercury(II). Structure of (2-Benzylpyridine)methylmercury(II) Nitrate


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Canty, AJ and Chaichit, N and Gatehouse, BM (1980) Weak Intramolecular Pi Coordination to Methylmercury(II). Structure of (2-Benzylpyridine)methylmercury(II) Nitrate. Acta Crystallographica Section B-Structural, B36 (P4). pp. 786-789. ISSN 0108-7681

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The title complex, [Hg(CH3)(C12HllN)]N03,C13HI4HgN+.N03-, has a linear C-Hg-N group with Hg-C 2·07(3) and Hg-N 2·10(2) A; there is a weak intramolecular pi interaction between Hg and a C=C bond of the phenyl ring with Hg-C distances of 3·23(2) and 3·33(3) A.

Item Type: Article
Journal or Publication Title: Acta Crystallographica Section B-Structural
Page Range: pp. 786-789
ISSN: 0108-7681
Identification Number - DOI: 10.1107/S0567740880004530
Additional Information: The definitive version is available at www.blackwell-synergy.com
Date Deposited: 05 Feb 2008 22:09
Last Modified: 18 Nov 2014 03:28
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