Library Open Repository
Smeets, WJJ and Spek, AL and Hoare, JL and Canty, AJ and Hovestad, NJ and van Koten, G (1997) (2,2'-Bipyridyl-N,N')dibromopalladium(II). Acta Crystallographica Section C, C53. pp. 1045-1047. ISSN 0108-2701
(2',2'-Bipyridy...pdf | Request a copy
Full text restricted
Available under University of Tasmania Standard License.
The title comlex, PdCl2(bipy), the 2,2'-bipyridine complex of palladium dichloride, has square-planar geometry for palladium with Pd-N 2.047(5) and Pd-Br 2.4102(9) Angstroms. The mean planes of the coordinated pyridine groups form a dihedral angle of 1.7(3) degrees with the coordination square plane; the parallel complexes stack with an interplanar spacing of 3.41(1) A and a Pd··Pd separation of 5.246(1) A to form a chain structure as reported for isomorphous PtI2(bipy) (where bipy is 2,2'-bipyridyl, C10H8N2). The structure differs from those found for related chain structures in the 'red' form of PtCl2(bipy) and in PdCl2(bipy) which is isomorphous with the 'yellow' form of PtCl2(bipy).
|Journal or Publication Title:||Acta Crystallographica Section C|
|Page Range:||pp. 1045-1047|
|Identification Number - DOI:||10.1107/S0108270197004149|
|Additional Information:||The definitive version is available at www.blackwell-synergy.com|
|Date Deposited:||25 Feb 2008 03:13|
|Last Modified:||18 Nov 2014 03:30|
|Item Statistics:||View statistics for this item|
Repository Staff Only (login required)
|Item Control Page|