Library Open Repository

(2,2'-Bipyridyl-N,N')dibromopalladium(II)

Downloads

Downloads per month over past year

Smeets, WJJ and Spek, AL and Hoare, JL and Canty, AJ and Hovestad, NJ and van Koten, G (1997) (2,2'-Bipyridyl-N,N')dibromopalladium(II). Acta Crystallographica Section C, C53. pp. 1045-1047. ISSN 0108-2701

[img] PDF
(2',2'-Bipyridyl-N,N)_dibromopalladuim.pdf | Request a copy
Full text restricted
Available under University of Tasmania Standard License.

Abstract

The title comlex, PdCl2(bipy), the 2,2'-bipyridine complex of palladium dichloride, has square-planar geometry for palladium with Pd-N 2.047(5) and Pd-Br 2.4102(9) Angstroms. The mean planes of the coordinated pyridine groups form a dihedral angle of 1.7(3) degrees with the coordination square plane; the parallel complexes stack with an interplanar spacing of 3.41(1) A and a Pd··Pd separation of 5.246(1) A to form a chain structure as reported for isomorphous PtI2(bipy) (where bipy is 2,2'-bipyridyl, C10H8N2). The structure differs from those found for related chain structures in the 'red' form of PtCl2(bipy) and in PdCl2(bipy) which is isomorphous with the 'yellow' form of PtCl2(bipy).

Item Type: Article
Journal or Publication Title: Acta Crystallographica Section C
Page Range: pp. 1045-1047
ISSN: 0108-2701
Identification Number - DOI: 10.1107/S0108270197004149
Additional Information: The definitive version is available at www.blackwell-synergy.com
Date Deposited: 25 Feb 2008 03:13
Last Modified: 18 Nov 2014 03:30
URI: http://eprints.utas.edu.au/id/eprint/3215
Item Statistics: View statistics for this item

Repository Staff Only (login required)

Item Control Page Item Control Page