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Crystal and Molecular Structure of (3,3'-Dimethyl-2,2'-bipyridyl)methylmercury(II) Nitrate; a Complex That May Have Weak Intramolecular pi-Coordination
Canty, AJ and Chaichit, N and Gatehouse, BM and Marker, A (1978) Crystal and Molecular Structure of (3,3'-Dimethyl-2,2'-bipyridyl)methylmercury(II) Nitrate; a Complex That May Have Weak Intramolecular pi-Coordination. Acta Crystallographica Section B-Structural, B34 (11). pp. 3229-3233. ISSN 0108-7681
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The structure of the methylmercury complex of 3,3'-dimethyl-2,2'-bipyridyl(L), [MeHg(L)]NO3, was solved by Patterson and Fourier techniques using 1560 counter-measured observed reflections and refined by the full-matrix least-squares method to R = 0·061. The complex has a bent C(1)-Hg-N(1) group [172·7(5)] with Hg-C(1) 2·01(1) and Hg-N(1) 2·11(1) A, weak interaction between mercury and nitrate oxygen atoms, and evidence suggesting the presence of a weak intramolecular-interaction between mercury and the second pyridyl ring, with Hg-C(2') 3·11(1), Hg-N(l') 3·29(1) A and an angle of 100·5 between the planes of the pyridyl rings.
|Journal or Publication Title:||Acta Crystallographica Section B-Structural|
|Page Range:||pp. 3229-3233|
|Identification Number - DOI:||10.1107/S0567740878010559|
The definitive version is available at www.blackwell-synergy.com
|Date Deposited:||18 Feb 2008 04:50|
|Last Modified:||18 Nov 2014 03:30|
|Item Statistics:||View statistics for this item|
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