Library Open Repository
Synthesis and Carbon-13 NMR Spectroscopy of Poly(pyrazol-1-yl)alkane Ligands
Byers, PK and Canty, AJ and Honeyman, RT and Claramunt, RM and Lopez, C and Lavandera, JL and Elguero, J (1992) Synthesis and Carbon-13 NMR Spectroscopy of Poly(pyrazol-1-yl)alkane Ligands. Gazzetta Chimica Italiana, 122 (9). pp. 341-344. ISSN 0016-5603
Gazz_1992,_341...pdf | Request a copy
Full text restricted
Available under University of Tasmania Standard License.
The use of polypyrazolylmethanes as ligands in coordination chemistry is increasing in an ever quicker pace. We here present a 13C NMR study of twelve bis- and tris-pyrazolylmethanes, eight of them never previously described. Those already known, bis(pyrazolyl)phenylmethane, tris(pyrazolyl)methane, tris(pyrazolyl)ethane, and tris(3,5-dimethylpyrazolyl)methane, have been extensively used in coordination chemistry. The carbon-13 chemical shifts show high internal consistency: for instance, a previously reported additive model predicts, with great accuracy, the chemical shift of the central sp3 carbon. Coupling constants proved to be useful tools for the assignment of pyrazole carbons. The 1J(IH-13C) coupling of the central carbon is linearly related to the basicity of the pyrazole substitutent in tris(pyrazol-1-yl)methanes.
|Journal or Publication Title:||Gazzetta Chimica Italiana|
|Page Range:||pp. 341-344|
The definitive version is available at http://www.sciencedirect.com
|Date Deposited:||18 Feb 2008 23:19|
|Last Modified:||18 Nov 2014 03:30|
|Item Statistics:||View statistics for this item|
Actions (login required)
|Item Control Page|