Library Open Repository

Organometallic Compounds Containing a Guanidinium Group. Crystal and Molecular Structure of (Creatinine)phenylmercury(II) Nitrate Monohydrate

Downloads

Downloads per month over past year

Canty, AJ and Chaichit, N and Gatehouse, BM (1979) Organometallic Compounds Containing a Guanidinium Group. Crystal and Molecular Structure of (Creatinine)phenylmercury(II) Nitrate Monohydrate. Acta Crystallographica Section B-Structural, B35 (5). pp. 592-596. ISSN 0108-7681

[img] PDF
AC_1979,_592.pdf | Request a copy
Full text restricted
Available under University of Tasmania Standard License.

Abstract

We have determined the structure of [PhHg(C4H7N30)][N03].H20. The crystal is made up of [PhHgNC(NH2)(Me)CH2CO]+ cations containing the phenylmercury group bonded to the ring N atom, nitrate ions, and water molecules. The creatinine and phenyl rings in the cation are almost coplanar, and the cations are stacked with phenyl and creatinine rings of adjacent ions almost parallel and 3·372 A apart. Bond lengths within the creatinine ring indicate delocalization of the carbonyl C(1)O with the guanidinium moiety as the C(1)-N(3) distance, 1·38 (4) A, is appropriate for multiple-bond character.

Item Type: Article
Journal or Publication Title: Acta Crystallographica Section B-Structural
Page Range: pp. 592-596
ISSN: 0108-7681
Identification Number - DOI: 10.1107/S0567740879004222
Additional Information: The definitive version is available at www.blackwell-synergy.com
Date Deposited: 19 Feb 2008 02:00
Last Modified: 18 Nov 2014 03:30
URI: http://eprints.utas.edu.au/id/eprint/3229
Item Statistics: View statistics for this item

Repository Staff Only (login required)

Item Control Page Item Control Page