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Organometallic Compounds Containing a Guanidinium Group. Crystal and Molecular Structure of (Creatinine)phenylmercury(II) Nitrate Monohydrate
Canty, AJ and Chaichit, N and Gatehouse, BM (1979) Organometallic Compounds Containing a Guanidinium Group. Crystal and Molecular Structure of (Creatinine)phenylmercury(II) Nitrate Monohydrate. Acta Crystallographica Section B-Structural, B35 (5). pp. 592-596. ISSN 0108-7681
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We have determined the structure of [PhHg(C4H7N30)][N03].H20. The crystal is made up of [PhHgNC(NH2)(Me)CH2CO]+ cations containing the phenylmercury group bonded to the ring N atom, nitrate ions, and water molecules. The creatinine and phenyl rings in the cation are almost coplanar, and the cations are stacked with phenyl and creatinine rings of adjacent ions almost parallel and 3·372 A apart. Bond lengths within the creatinine ring indicate delocalization of the carbonyl C(1)O with the guanidinium moiety as the C(1)-N(3) distance, 1·38 (4) A, is appropriate for multiple-bond character.
|Journal or Publication Title:||Acta Crystallographica Section B-Structural|
|Page Range:||pp. 592-596|
|Identification Number - DOI:||10.1107/S0567740879004222|
|Additional Information:||The definitive version is available at www.blackwell-synergy.com|
|Date Deposited:||19 Feb 2008 02:00|
|Last Modified:||18 Nov 2014 03:30|
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