Dimethylpalladium(II) and Monomethylpalladium(II) Reagents and Complexes

Byers, PK and Canty, AJ and Jin, H and Kruis, D and Markies, BA and Boersma, J and van Koten, G and Hill, GS and Irwin, MJ and Rendina, LM and Puddephatt, RJ (1998) Dimethylpalladium(II) and Monomethylpalladium(II) Reagents and Complexes. Inorganic Syntheses, 32 . pp. 162-172. ISSN 0073-8077

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Abstract

Syntheses of organopalladium(II) reagents containing N,N,N',N'-tetramethylethylenediamine (tmeda), pyridazine, dimethylsulfide, 2,2'-bipyridine (bpy), triphenylphosphine and bis(1,1'-diphenylphosphino)ferrocene (dppf) are described, together with trans-dichlorobis(dimethylsulfide)palladium(II) and trans-dibromobis(dimethylsulfide)palladium(II). Syntheses are described for dimethyl(pyridazine)palladium(II), monomethylpalladium(II) complexes of dimethylsulfide, [PdMe(SMe2)(mu-X)]2 (X = Cl, Br, I), PdMe2(tmeda) and PdXMe(tmeda) (X = Cl, Br, I), PdMe2(dppf) and PdXMe(dppf) (X = Cl, Br, I), cis-PdMe2(PPh3)2 and trans-PdClMe(PPh3)2 (X = Cl, Br, I), and trans-PdXMe(bpy) (X = Cl, Br, I).

Item Type:	Article
Additional Information:	restricted - published John Wiley & Sons, Inc Sherpa -"On personal web site only Published source must be acknowledged with set phrase Publisher's version/PDF cannot be used Articles in some journals can be made Open Access on payment of additional charge
ID Code:	3354
Deposited By:	Prof Allan J Canty
Deposited On:	04 Mar 2008 09:30
Last Modified:	18 Jul 2008 20:38
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