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Use of linear solvation energy relationships for characterization of hypercrosslinked polystyrene stationary phases

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Nesterenko, EP and Skornyakov, VI and Nesterenko, PN and Ivanov, AV (2008) Use of linear solvation energy relationships for characterization of hypercrosslinked polystyrene stationary phases. Moscow University Chemistry Bulletin, 63 (1). pp. 23-29. ISSN 0027-1314

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Abstract

Linear solvation energy relationships (LSER model) was tested for the characterization of hypercrosslinked polystyrene (HCPS) stationary phases for high-performance liquid chromatography (HPLC). Analysis of LSER coefficients showed that hydrophobic and electrostatic interactions are the major contributors to retention on HCPS. Fluorine atoms in HCPS increase the fractions of both hydrophobic and electrostatic interactions in the retention. The utility of fluorinated HCPS in the separation of din -phthalate mixtures by reversed-phase liquid chromatography was demonstrated.

Item Type: Article
Journal or Publication Title: Moscow University Chemistry Bulletin
Page Range: pp. 23-29
ISSN: 0027-1314
Identification Number - DOI: 10.3103/S0027131408010069
Date Deposited: 16 Mar 2008 23:22
Last Modified: 18 Nov 2014 03:31
URI: http://eprints.utas.edu.au/id/eprint/3464
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