Buckling under Strain: Relief of Steric Pressure Occurs Differently for Samarium(III) Porphyrinogen Complexes of the ?-bound Auxiliary Ligands Cyclopentadienyl and Cyclooctatetraenediyl

Frey, ASP and Gardiner, MG and Stringer, DN and Yates, BF and George, AV and Jensen, P and Turner, Paul (2007) Buckling under Strain: Relief of Steric Pressure Occurs Differently for Samarium(III) Porphyrinogen Complexes of the ?-bound Auxiliary Ligands Cyclopentadienyl and Cyclooctatetraenediyl. Organometallics, 26 (6). pp. 1299-1302. ISSN 0276-7333

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Official URL: http://dx.doi.org/10.1021/om061143i

Abstract

The most adhered to strategy in inorganic chemistry for stabilizing reactive functionalities, achieving reaction selectivities, and accessing novel structural motifs is the use of hindered “nonparticipative ligands” to afford protection and/or force unusual/desired behavior.

Item Type:	Article
ID Code:	3732
Deposited By:	HERDC System Editor
Deposited On:	08 Apr 2008 00:04
Last Modified:	18 Jul 2008 20:45
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