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Ethylene Tri- and Tetramerization with Borate Cocatalysts: Effects on Activity, Selectivity, and Catalyst Degradation Pathways

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McGuinness, DS and Overett, M and Tooze, RP and Blann, K and Dixon, JT and Slawin, AMZ (2007) Ethylene Tri- and Tetramerization with Borate Cocatalysts: Effects on Activity, Selectivity, and Catalyst Degradation Pathways. Organometallics, 26 (4). pp. 1108-1111. ISSN 0276-7333

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Abstract

In recent years the chromium-catalyzed oligomerization of
ethylene to linear R-olefins (LAOs) has been extensively studied
both in industry and in academia, due in part to increased
demand for LAOs, particularly the co-monomers 1-hexene and
1-octene. Recent work includes the development of increasingly
more active systems for full-range oligomerization,1 a variety
of Cr-based ethylene trimerization systems,2-4 and the first
example of selective ethylene tetramerization to 1-octene.5

Item Type: Article
Journal or Publication Title: Organometallics
Publisher: American Chemical Society
Page Range: pp. 1108-1111
ISSN: 0276-7333
Identification Number - DOI: 10.1021/om060906z
Additional Information:

Copyright © 2007 American Chemical Society

Date Deposited: 07 Apr 2008 14:38
Last Modified: 18 Nov 2014 03:35
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