Due to routine maintenance, access to the Library Open Repository will be interrupted on the morning of Friday 12th February.
We apologise for any inconvenience.

Library Open Repository

Microfluidic devices for flow-through supported palladium catalysis on porous organic monolith

Downloads

Downloads per month over past year

Canty, AJ and Deverell, JA and Gomann, A and Guijt, RM and Rodemann, T and Smith, JA (2008) Microfluidic devices for flow-through supported palladium catalysis on porous organic monolith. Australian Journal of Chemistry, 61 (8). pp. 630-633. ISSN 0004-9425

[img] PDF
AustJChem_2008...pdf | Request a copy
Full text restricted

Abstract

Flow-through microreactors are described, constructed of fused silica capillaries with an internal diameter of 100μm and glass microchips with a channel dimension of 150μm and involving the in situ UV-initiated synthesis of a poly(glycidyl methacrylate-co-ethylene dimethacrylate) porous polymer monolith. The monolith is a continuous material covalently bonded to the capillary or chip walls, with good flow-through properties. Epoxide ring-opening through amine attack by 5-amino-1,10-phenanthroline and coordination to dichloropalladium(ii) allows use of the microreactors for Suzuki–Miyaura catalysis. The long-term stability and reliability of the robust lab on a chip microreactor is demonstrated by operation for 96 h, exhibiting undiminished reactivity, and very low leaching of palladium.

Item Type: Article
Keywords: lab on a chip, capillary, supported catalysis, palladium catalysis, Suzuki, organic monolith, microreactor
Journal or Publication Title: Australian Journal of Chemistry
Page Range: pp. 630-633
ISSN: 0004-9425
Identification Number - DOI: 10.1071/CH08160
Additional Information: © CSIRO 2008
Date Deposited: 17 Aug 2008 22:34
Last Modified: 18 Nov 2014 03:48
Item Statistics: View statistics for this item

Repository Staff Only (login required)

Item Control Page Item Control Page