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Separation of metal ions and metal-containing species by micellar electrokinetic capillary chromatography, including utilisation of metal ions in separations of other species

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Haddad, PR and Macka, M and Hilder, EF and Bogan, DP (1997) Separation of metal ions and metal-containing species by micellar electrokinetic capillary chromatography, including utilisation of metal ions in separations of other species. Journal of Chromatography A, 780 (1-2). pp. 329-341. ISSN 0021-9673

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Abstract

The use of micellar electrokinetic capillary chromatography (MEKC) for the separation of metal ions and metal-containing species is reviewed, together with the use of metal ions as a means to separate other species. Topics covered include the manipulation of separation selectivity through the use of complexation reactions induced by addition of a metal ion to the background electrolyte, enantiomeric separations facilitated through metal-analyte interactions, separation of organometallic species, separation of stable metal complexes in which the entire complex is the analyte and the separation of metal ions as analytes using pre-capillary or on-capillary complexation reactions with a suitable ligand.

Item Type: Article
Keywords: Reviews; Background electrolyte composition; Enantiomer separation; Metal cations; Metal complexes; Organometallic compounds
Journal or Publication Title: Journal of Chromatography A
Page Range: pp. 329-341
ISSN: 0021-9673
Identification Number - DOI: 10.1016/S0021-9673(97)00373-7
Additional Information: The definitive version is available at http://www.sciencedirect.com
Date Deposited: 23 Sep 2008 03:41
Last Modified: 18 Nov 2014 03:49
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