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The effect of butan-1-ol on the separation of inorganic Nions using capillary zone electrophoresis with reversed electroosmotic flow

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Harakuwe, AH and Haddad, PR and Thomas, R (1999) The effect of butan-1-ol on the separation of inorganic Nions using capillary zone electrophoresis with reversed electroosmotic flow. Journal of Liquid Chromatography & Related Technologies, 22 (5). pp. 659-667. ISSN 1082-6076

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Abstract

The separation selectivity of inorganic anions in capillary zone electrophoresis with reversed electroosmotic flow was altered by incorporating ≤7.5% v/v butan-1-ol in a chromate-based background electrolyte (BGE). Pronounced selectivity changes occurred for lipophilic anions, whereas, for the common inorganic anions, the changes were minor. The likely causes for these selectivity changes are discussed. Furthermore, BGEs with butan-1-ol yielded separations with (i) short times for lipophilic anions, (ii) smoother baselines, (iii) better resolutions, (iv) increased peak heights for iodide and thiocyanate, and (v) good reproducibility (≤4% RSD, n = 11) for absolute migration time, peak area, and peak height.

Item Type: Article
Journal or Publication Title: Journal of Liquid Chromatography & Related Technologies
Page Range: pp. 659-667
ISSN: 1082-6076
Identification Number - DOI: 10.1081/JLC-100101688
Additional Information: The definitive published version is available online at: http://www.tandf.co.uk/journals
Date Deposited: 31 Oct 2008 06:25
Last Modified: 18 Nov 2014 03:53
URI: http://eprints.utas.edu.au/id/eprint/7947
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