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Separation of metal Bis(2-hydroxyethyl)dithiocarbamate complexes by micellar electrokinetic capillary chromatography
Hilder, EF and Macka, M and Bogan, DP and Haddad, PR (1997) Separation of metal Bis(2-hydroxyethyl)dithiocarbamate complexes by micellar electrokinetic capillary chromatography. Analytical Communications, 34 (2). pp. 63-65. ISSN 1359-7337
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A method was developed for the separation of CdII, PbII, PtII, CoII, NiII, BiIII, CrII, CuII and HgII bis(2-hydroxyethyl)dithiocarbamate (HEDTC) complexes by micellar electrokinetic capillary chromatography. The complexes were formed by pre-capillary reaction of the metal ions with an excess of the ligand and then separated using a 100 mM borate buffer (pH 9.2) containing 4% methanol (v/v), 10 mM sodium dodecyl sulfate and 0.1 mM HEDTC, with detection at 254 nm. All the metal complexes, except PtII and PbII, were baseline resolved and separation was achieved in under 7 min. Detection limits were in the range 22 to 133 ppb.
|Journal or Publication Title:||Analytical Communications|
|Page Range:||pp. 63-65|
|Identification Number - DOI:||10.1039/A607770F|
|Additional Information:||© 1997 Royal Society of Chemistry|
|Date Deposited:||13 Nov 2008 02:28|
|Last Modified:||18 Nov 2014 03:53|
|Item Statistics:||View statistics for this item|
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