creators_name: Canty, AJ
creators_name: Skelton, BW
creators_name: White, AH
creators_id: allan.canty@utas.edu.au
creators_id: 
creators_id: 
type: article
datestamp: 2008-02-04 22:09:18
lastmod: 2008-07-18 10:30:18
metadata_visibility: show
title: Structural studies of complexes containing cycloplatinated
tris(pyrazol-1-yl)methane
ispublished: pub
subjects: 259901
full_text_status: restricted
note: The definitive version is available at http://www.sciencedirect.com
abstract: Cyclometallation at the C(5) position of one ring of tris(pyrazol-1-yl)methane occurs on dissolutionof PtMe2{(pz)3CH} in 3,5-dimethylpyridine, to form the platinum(II) complex PtMe((pz)2(C3H2N2)-CH-N,C)(3,5-Me2py) (lb). Structural studies of lb, and the related complexes PtMe{(pz)3(C3H2N2)-CH-N,C}(N-methylimidazole) (1c) and PtMe{(pz)2(C3H2N2)CH- N,C}{PPh2(o-MeOC6H4)} (ld) show that these complexes have square planar geometry with cis-organic groups, with the cyclometallated group having one pyrazole ring uncoordinated. The complexes PtMe{(pz)2(C3H2N2)CH-C}(L2) (L2 = 2PPh3 (2a), 2PEtPh, (2b), Ph2PCH2CH2PPh2 (2c)] have a similar geometry at platinum(II); the metallated ligand is present as a [C]- donor with two uncoordinated pyrazole rings. In 2a, 2b, and 2c,
there are short Pt...H contacts at ~2.7 A for the methine proton of the cyclometallated ligand.
date: 1992
date_type: published
publication: Journal of Organometallic Chemistry
volume: 430
number: 2
pagerange: 245-257
id_number: 10.1016/0022-328X(92)86011-R
refereed: TRUE
issn: 0022-328X
official_url: http://dx.doi.org/10.1016/0022-328X(92)86011-R
citation: Canty, AJ and Skelton, BW and White, AH (1992) Structural studies of complexes containing cycloplatinated tris(pyrazol-1-yl)methane. Journal of Organometallic Chemistry, 430 (2). pp. 245-257. ISSN 0022-328X
document_url: http://eprints.utas.edu.au/2957/1/JOMC1992_2C_245.pdf