@article{epprod3845, volume = {23}, number = {5}, month = {["lib/utils:month\verb1_13845" not defined]}, author = {Y Miura and N Takenami and PR Haddad}, note = {2007 \copyright The Japan Society for Analytical Chemistry}, title = {Ion-interaction chromatography of several metallocyanide complexes stabilized by adding cyanide in a neutral mobile phase}, publisher = {Japanese Society for Analytical Chemistry}, year = {2007}, journal = {Analytical Sciences}, pages = {605--609}, url = {http://eprints.utas.edu.au/3845/}, abstract = {Standard solutions (at 10?5 M levels) of Cu(I)- and Fe(II)-cyanide complexes were stabilized for at least 5 h using 0.5 mM cyanide solution (around pH 9) as a medium. Complexes of Cu(I)- and Fe(III)-cyanide also could be stabilized without any dissociation by adding 1 mM cyanide to an acetonitrile?water (18:82, v/v) mobile phase (pH 7.0) containing 10 mM tetra-n-propylammonium salt (TPA). Under the optimal conditions, the six complexes of Cu(I)-, Ag(I)-, Ni(II)-, Fe(II)-, Fe(III)- and Au(I)-cyanides were resolved from their mixtures within about 45 min, with well-shaped chromatographic peaks.} }