6422 26 archive 310 disk0/00/00/64/22 2008-05-19 12:19:25 2008-09-11 01:37:55 2008-07-16 17:24:11 article show Paul.Haddad@utas.edu.au Breadmore MC mcb@utas.edu.au Hilder EF Emily.Hilder@utas.edu.au Macka M Mirek.Macka@utas.edu.au Haddad PR Paul.Haddad@utas.edu.au pub 030108 250000 250401 250400 970103 780103 restricted Capillary electrochromatography; Selectivity manipulation; Inorganic anion; Mixed-mode separation The definitive version is available online at http://www.sciencedirect.com/ Recent advances in the separation of inorganic anions by capillary electrochromatography (CEC) are reviewed. Due to the nature of these analytes, the area is dominated by use of ion-exchange (IE) stationary phases in packed, open-tubular or pseudo-phase columns. The strengths and weaknesses of each format in the IE mode are compared and discussed. It is shown that the selectivity of these systems can be modelled accurately using physical retention models and that these models can subsequently be used for method optimisation. Further developments in the field which can be expected in the near future are also discussed. 2001-06 published TrAC - Trends in Analytical Chemistry 20 6-7 355-364 10.1016/S0165-9936(01)00073-5 TRUE 0167-2940 http://dx.doi.org/10.1016/S0165-9936(01)00073-5 1. P.R. Haddad. J. Chromatogr. A 770 (1997), p. 281. 2. D. Li, H.H. Knobel and V.T. Remcho. J. Chromatogr. B 695 (1997), p. 169. 3. S. Kitagawa, A. Tsuji, H. Watanabe, M. Nakashima and T. Tsuda. J. Microcol. Sep. 9 (1997), p. 347. 4. E.F. Hilder, Ion-exchange capillary electrochromatography of inorganic and small organic anions, PhD Dissertation, University of Tasmania, 2000. 5. E.F. Hilder, C.W. Klampfl and P.R. Haddad. J. Chromatogr. A 890 (2000), p. 337. 6. E.F. Hilder, M. Macka and P.R. Haddad. Anal. Commun. 36 (1999), p. 299. 7. E.F. Hilder, A.J. Zeeman, M. Macka, P.R. Haddad, Electrophoresis, in press. 8. J.J. Pesek and M.T. Matyska. J. Chromatogr. A 887 (2000), p. 31. 9. M.S. Nutku and F.B. Erim. J. High Resol. Chromatogr. 21 (1998), p. 505. 10. M.C. Breadmore, M. Macka and P.R. Haddad. Analyst 125 (2000), p. 1235. 11. M. Boyce, M.C. Breadmore, M. Macka, P.A. Doble and P.R. Haddad. Electrophoresis 20 (2000), p. 3073. 12. M.C. Breadmore, M. Boyce, M. Macka, N. Avdalovic and P.R. Haddad. Analyst 125 (2000), p. 799. 13. M.C. Breadmore, M. Macka, N. Avdalovic, P.R. Haddad, Anal. Chem., in press. 14. M.C. Breadmore, A.S. Palmer, M. Macka, N. Avdalovic, P.R. Haddad, in preparation. 15. S. Terabe, K. Otsuka and T. Ando. Anal. Chem. 57 (1985), p. 834. 16. S. Terabe, K. Otsuka, K. Ichikawa, A. Tsuchiya and T. Ando. Anal. Chem. 1984 (1984), p. 111. 17. M.G. Khaledi. J. Chromatogr. A 780 (1997), p. 3. 18. V. Schurig and D. Wistuba. Electrophoresis 20 (1999), p. 2313. 19. C.P. Palmer. J. Chromatogr. A 780 (1997), p. 75. 20. B. Göttlicher and K. Bächmann. J. Chromatogr. A 780 (1997), p. 63. 21. K.D. Altria. J. Chromatogr. A 892 (2000), p. 171. 22. W.R. Jones and P. Jandik. J. Chromatogr. 546 (1991), p. 445. 23. C.A. Lucy. J. Chromatogr. A 850 (1999), p. 319. 24. C. Stathakis and R.M. Cassidy. Anal. Chem. 66 (1994), p. 667. 25. C. Stathakis and R.M. Cassidy. J. Chromatogr. A 699 (1995), p. 353. 26. O.V. Krokhin, H. Hoshino, O.A. Shpigun and T. Yotsuyanagi. J. Chromatogr. A 776 (1997), p. 329. 27. J. Li, W. Ding and J.S. Fritz. J. Chromatogr. A 879 (2000), p. 245. 28. M.C. Breadmore, P.R. Haddad, J.S. Fritz, J. Chromatogr. A, in press. 29. C. Stathakis and R.M. Cassidy. Can. J. Chem. 76 (1998), p. 194. 30. M.A. Woodland, C.A. Lucy, Analyst, in press. 31. M.C. Breadmore, E.F. Hilder, M. Macka, P.R. Haddad, Electrophoresis, in press. 32. M.C. Breadmore, P.R. Haddad and J.S. Fritz. Electrophoresis 20 (2000), p. 3181. 5276 4 6422 1 application/pdf en staffonly cc_utas

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