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Organolanthanide chemistry of modified porphyrinogens
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Abstract
This thesis describes studies into the synthesis, characterisation and reactivity
of samarium(II) and (Ill) halide, alkyl and amide complex~s derived from the
modified porphyrinogens meso-octaethyl-trans-dioxaporphyrinogen, Et8O2N2H2, and
trans-N,N'-dimethyl-meso-octaethylporphyrinogen, Et8NMe2H2. The macrocycles
themselves and various Group 1 metal derivatives that are accessed in the
preparation of the target lanthanide complexes are also described in relation to their
synthesis, characterisation and reactivity.
Item Type: | Thesis - PhD |
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Authors/Creators: | Wang, Jun |
Keywords: | Organorare earth metal compounds, Lanthanum compounds, Porphyrins |
Copyright Holders: | The Author |
Copyright Information: | Copyright 2003 the Author - The University is continuing to endeavour to trace the copyright |
Additional Information: | Thesis (Ph.D.)--University of Tasmania, 2003. Includes bibliographical references |
Item Statistics: | View statistics for this item |
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