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A one-pot route to thioamides discovered by gas-phase studies: palladium-mediated CO2 extrusion followed by insertion of isothiocyanates

Noor, A, Li, J, Khairallah, GN, Li, Z, Ghari, H, Canty, AJ, Ariafard, A, Donnelly, PS and O'Hair, RAJ 2017 , 'A one-pot route to thioamides discovered by gas-phase studies: palladium-mediated CO2 extrusion followed by insertion of isothiocyanates' , Chemical Communications, vol. 53, no. 27 , pp. 3854-3857 , doi: 10.1039/c7cc00865a.

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Abstract

A new palladium mediated “one pot” synthesis of thioamides from aromatic carboxylic acids (ArCO2H + RNCS → ArC(S)NHR + CO2) was discovered by gas-phase experiments and theoretical studies. Palladium-mediated decarboxylation of aromatic carboxylic acids followed by addition of substituted isothiocyanates leads to the corresponding thioamide derivatives.

Item Type: Article
Authors/Creators:Noor, A and Li, J and Khairallah, GN and Li, Z and Ghari, H and Canty, AJ and Ariafard, A and Donnelly, PS and O'Hair, RAJ
Keywords: metal mediated synthesis, thioamide synthesis, organopalladium
Journal or Publication Title: Chemical Communications
Publisher: Royal Soc Chemistry
ISSN: 1359-7345
DOI / ID Number: 10.1039/c7cc00865a
Copyright Information:

© The Royal Society of Chemistry 2017

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