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A one-pot route to thioamides discovered by gas-phase studies: palladium-mediated CO2 extrusion followed by insertion of isothiocyanates
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Noor, A, Li, J, Khairallah, GN, Li, Z, Ghari, H, Canty, AJ, Ariafard, A, Donnelly, PS and O'Hair, RAJ 2017
, 'A one-pot route to thioamides discovered by gas-phase studies: palladium-mediated CO2 extrusion followed by insertion of isothiocyanates'
, Chemical Communications, vol. 53, no. 27
, pp. 3854-3857
, doi: 10.1039/c7cc00865a.
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Official URL: http://dx.doi.org/10.1039/c7cc00865a
Abstract
A new palladium mediated “one pot” synthesis of thioamides from aromatic carboxylic acids (ArCO2H + RNCS → ArC(S)NHR + CO2) was discovered by gas-phase experiments and theoretical studies. Palladium-mediated decarboxylation of aromatic carboxylic acids followed by addition of substituted isothiocyanates leads to the corresponding thioamide derivatives.
| Item Type: | Article |
|---|---|
| Authors/Creators: | Noor, A and Li, J and Khairallah, GN and Li, Z and Ghari, H and Canty, AJ and Ariafard, A and Donnelly, PS and O'Hair, RAJ |
| Keywords: | metal mediated synthesis, thioamide synthesis, organopalladium |
| Journal or Publication Title: | Chemical Communications |
| Publisher: | Royal Soc Chemistry |
| ISSN: | 1359-7345 |
| DOI / ID Number: | 10.1039/c7cc00865a |
| Copyright Information: | © The Royal Society of Chemistry 2017 |
| Related URLs: | |
| Item Statistics: | View statistics for this item |
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