Open Access Repository
Ligand-induced decarbonylation in diphosphine-ligated palladium acetates [CH3CO2Pd((PR2)2CH2)]+ (R = Me and Ph)
Altmetric
Altmetric
Altmetric
Lesslie, M, Yang, Y, Canty, AJ, Piacentino, E, Berthias, F, Maitre, P, Ryzhov, V and O'Hair, RAJ 2018
, 'Ligand-induced decarbonylation in diphosphine-ligated palladium acetates [CH3CO2Pd((PR2)2CH2)]+ (R = Me and Ph)'
, Chemical Communications, vol. 54
, pp. 346-349
, doi: https://doi.org/10.1039/C7CC08944A.
Full text not available from this repository.
Official URL: http://dx.doi.org/10.1039/C7CC08944A
Abstract
A new decarbonylation reaction is observed for [(K2-acetate)Pd(K2-diphosphine)]+ complexes. Gas-phase IR experiments identify the product as [CH3Pd(OP(Ph2)CH2PPh2)]+. DFT calculations uncovered a plausible mechanism involving O atom abstraction by the diphosphine ligand within the coordination sphere to yield the acetyl complex, [CH3COPd(OP(Ph2)CH2PPh2)]+, which then undergoes decarbonylation.
| Item Type: | Article |
|---|---|
| Authors/Creators: | Lesslie, M and Yang, Y and Canty, AJ and Piacentino, E and Berthias, F and Maitre, P and Ryzhov, V and O'Hair, RAJ |
| Keywords: | palladium, organopalladium, DFT, mass spectrometry, organometallic mechanism |
| Journal or Publication Title: | Chemical Communications |
| Publisher: | Royal Soc Chemistry |
| ISSN: | 1359-7345 |
| DOI / ID Number: | https://doi.org/10.1039/C7CC08944A |
| Copyright Information: | Copyright 2018 The Royal Society of Chemistry |
| Related URLs: | |
| Item Statistics: | View statistics for this item |
Actions (login required)
 |
Item Control Page |