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Transition metal organometallic synthesis utilising diorganoiodine(III) reagents

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Canty, AJ and Rodemann, T and Ryan, JH (2007) Transition metal organometallic synthesis utilising diorganoiodine(III) reagents. In: Advances in Organometallic Chemistry. Academic Press, USA, pp. 279-313. ISBN 0123739780

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Abstract

Hypervalent iodine reagents have a prominent role in organic synthesis, but there is only a slowly emerging chemistry employing these reagents for transition metal organometallic synthesis, despite the early promising results reported in the 1960s, and extensive reports of the application of diorganoiodine(III) reagents in organic synthesis involving metal centres. This review summarises the fundamental aspects of mechanisms proposed for organic chemistry applications, reviews representative reports in organometallic chemistry with this perspective, and highlights the potential for further developments in the field.

Item Type: Book Section
Keywords: Iodonium Organometallic Diorganoiodine(III), Oxidation Organic synthesis Alkynyl Alkenyl Iodine(III)
Publisher: Academic Press
Page Range: pp. 279-313
Date Deposited: 13 Dec 2007 00:51
Last Modified: 18 Nov 2014 03:26
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