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Polygodial: a viable natural product scaffold for the rapid synthesis of novel polycyclic pyrrole and pyrrolidine derivatives
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Rihak, KJ, Bissember, AC 
ORCID: 0000-0001-5515-2878 and Smith, JA ORCID: 0000-0001-6313-3298 2018
, 'Polygodial: a viable natural product scaffold for the rapid synthesis of novel polycyclic pyrrole and pyrrolidine derivatives'
, Tetrahedron, vol. 74, no. 12
, pp. 1167-1174
, doi: 10.1016/j.tet.2017.10.015.
ORCID: 0000-0001-5515-2878 and Smith, JA ORCID: 0000-0001-6313-3298 2018
, 'Polygodial: a viable natural product scaffold for the rapid synthesis of novel polycyclic pyrrole and pyrrolidine derivatives'
, Tetrahedron, vol. 74, no. 12
, pp. 1167-1174
, doi: 10.1016/j.tet.2017.10.015.
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Abstract
The dialdehyde polygodial was utilised as a chiral scaffold for the unified synthesis of novel polycyclic pyrrole and pyrrolidine derivatives. Mechanistic insight into the reaction of primary amines with this dialdehyde was obtained. In addition, one of these polycyclic pyrroles was transformed further to prepare novel pentacyclic frameworks.
| Item Type: | Article |
|---|---|
| Authors/Creators: | Rihak, KJ and Bissember, AC and Smith, JA |
| Keywords: | polygodial, pyrrole, natural products, chiral synthetic scaffolds |
| Journal or Publication Title: | Tetrahedron |
| Publisher: | Pergamon-Elsevier Science Ltd |
| ISSN: | 0040-4020 |
| DOI / ID Number: | 10.1016/j.tet.2017.10.015 |
| Copyright Information: | Copyright 2017 Elsevier Ltd. |
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| Item Statistics: | View statistics for this item |
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