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α-Cyanocarbanion complexes and their application in synthesis
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Bissember, AC 
ORCID: 0000-0001-5515-2878, Gardiner, MG ORCID: 0000-0001-6373-4253 and Wierenga, TS 2018
, 'α-Cyanocarbanion complexes and their application in synthesis'
, Journal of Organometallic Chemistry, vol. 869
, pp. 213-226
, doi: 10.1016/j.jorganchem.2018.04.010.
ORCID: 0000-0001-5515-2878, Gardiner, MG ORCID: 0000-0001-6373-4253 and Wierenga, TS 2018
, 'α-Cyanocarbanion complexes and their application in synthesis'
, Journal of Organometallic Chemistry, vol. 869
, pp. 213-226
, doi: 10.1016/j.jorganchem.2018.04.010.
Full text not available from this repository.
Official URL: https://doi.org/10.1016/j.jorganchem.2018.04.010
Abstract
α-Cyanocarbanion complexes feature nitrile ligands containing deprotonated α-carbon atoms. This short review will focus on the various synthetic methods employed to prepare these complexes, the different binding modes they exhibit and their applications to the synthesis of alkylnitriles including β-hydroxyand β-aminonitriles, the formation of unique coupling products and as key intermediates in the reaction of acrylonitrile with various substrates in hydrophosphination and copolymerisation reactions.
| Item Type: | Article |
|---|---|
| Authors/Creators: | Bissember, AC and Gardiner, MG and Wierenga, TS |
| Keywords: | Cyanocarbanion, C-H activation, nitrile, ketenimine, catalysis |
| Journal or Publication Title: | Journal of Organometallic Chemistry |
| Publisher: | Elsevier Science Sa |
| ISSN: | 0022-328X |
| DOI / ID Number: | 10.1016/j.jorganchem.2018.04.010 |
| Copyright Information: | © 2018 Elsevier B.V. All rights reserved. |
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| Item Statistics: | View statistics for this item |
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