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Chloro(phenyl)(1H-pyrazole-KN2)-(triphenylphosphine-KP)palladium(II)

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Canty, AJ and Skelton, BW and White, AH (2004) Chloro(phenyl)(1H-pyrazole-KN2)-(triphenylphosphine-KP)palladium(II). Acta Crystallographica Section C, C60. m405-m406. ISSN 0108-2701

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Abstract

In the title compound, [Pd(C6H5)Cl(C3H4N2){P(C6H5)3}], PdClPh(pyrazole)(PPh3), the phenyl and Cl ligands lie mutually trans. The compound is the first structurally characterized complex with four monodentate Cl, P, N and (non-carbenoid) C ligands in a squareplanar four-coordinate palladium(II) environment. The pyrazole ligand is coplanar with the latter array. The pyrazole NH group forms a bifurcated hydrogen bond to Cl, with an intra and intermolecular component.

Item Type: Article
Journal or Publication Title: Acta Crystallographica Section C
Page Range: m405-m406
ISSN: 0108-2701
Identification Number - DOI: 10.1107/S010827010401491X
Additional Information:

"The definitive version is available at www.blackwell-synergy.com"

Date Deposited: 21 Dec 2007 03:52
Last Modified: 18 Nov 2014 03:26
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