Open Access Repository

Bis[tris(pyridin-2-yl)methanol-K2N,N']palladium(II) dinitrate at 150 and 298 K

Downloads

Downloads per month over past year

Canty, AJ, Skelton, BW, Traill, PR and White, AH 2004 , 'Bis[tris(pyridin-2-yl)methanol-K2N,N']palladium(II) dinitrate at 150 and 298 K' , Acta Crystallographica Section C, vol. C60, No. part 7 , m305-m307 , doi: 10.1107/S0108270104010893.

[img] PDF
AC2C_C602C_m305...pdf | Request a copy
Full text restricted
Available under University of Tasmania Standard License.

Abstract

The title complex, [Pd{(py)3COH}2](NO3)2, where (py)3COH is tris(pyridin-2-yl)methanol (C16H13N3O), studied at 150 and 298 K, has the potentially tridentate ligands present as bidentate ligands, with the Pd atom at a centre of symmetry. At 150 K, the PdÐN distances are 2.022 (3) and 2.026 (3) A. The mean planes of the coordinated pyridine groups form dihedral angles of 42.1 (1) and 45.3 (1) degrees (at 150 K) with the coordination plane; the uncoordinated rings situated either side of the coordination plane form dihedral angles of 42.2 (1)degrees with it. The nitrate ions are regular and interact weakly with the hydroxyl group.

Item Type: Article
Authors/Creators:Canty, AJ and Skelton, BW and Traill, PR and White, AH
Journal or Publication Title: Acta Crystallographica Section C
ISSN: 0108-2701
DOI / ID Number: 10.1107/S0108270104010893
Additional Information:

"The definitive version is available at www.blackwell-synergy.com"

Item Statistics: View statistics for this item

Actions (login required)

Item Control Page Item Control Page
TOP