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Synthesis and Structures of the Ligands 1-Methylimidazol-2-yl(pyridin-2-yl)-methanone {(py)(mim)CO} and 1-Benzylimidazol-2-yl(1-phenylaldimine)(PhN=CHbim) as their Tetracarbonylmolybdenum(0) Complexes[Mo(CO)4(L2-N,N')]
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Batten, MP, Canty, AJ, Cavell, KJ, Skelton, BW and White, AH 2006
, 'Synthesis and Structures of the Ligands 1-Methylimidazol-2-yl(pyridin-2-yl)-methanone {(py)(mim)CO} and 1-Benzylimidazol-2-yl(1-phenylaldimine)(PhN=CHbim) as their Tetracarbonylmolybdenum(0) Complexes[Mo(CO)4(L2-N,N')]'
, Zeitschrift fur Anorganische und Allgemein Chemie, vol. 632, no. 5
, pp. 876-878
, doi: https://doi.org/10.1002/zaac.200500531.
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ZAAC_876.pdf | Request a copy Full text restricted Available under University of Tasmania Standard License. |
Official URL: http://dx.doi.org/10.1002/zaac.200500531
Abstract
The complexes [Mo(CO)4(L2-N,N')] [L2 = 1-methylimidazol-
2-yl(pyridin-2-yl)methanone and 1-benzylimidazol-2-yl(1-
phenylaldimine)] have been synthesized from hexacarbonylmolybdenum(0) in order to define the coordination characteristics of the bidentate nitrogen-donor ligands; the complexes exhibit distorted octahedral coordination for molybdenum(0) and cis-bidentate ligand
configurations.
Item Type: | Article |
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Authors/Creators: | Batten, MP and Canty, AJ and Cavell, KJ and Skelton, BW and White, AH |
Keywords: | Molybdenum; Carbonyl; Imidazole; Crystal structure |
Journal or Publication Title: | Zeitschrift fur Anorganische und Allgemein Chemie |
ISSN: | 0044-2313 |
DOI / ID Number: | https://doi.org/10.1002/zaac.200500531 |
Additional Information: | "Submitted to/accepted for publication in (Zeitschrift fur Anorganische und Allgemein Chemie) (2006) WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim", |
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