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Synthesis and Structures of the Ligands 1-Methylimidazol-2-yl(pyridin-2-yl)-methanone {(py)(mim)CO} and 1-Benzylimidazol-2-yl(1-phenylaldimine)(PhN=CHbim) as their Tetracarbonylmolybdenum(0) Complexes[Mo(CO)4(L2-N,N')]

Batten, MP, Canty, AJ, Cavell, KJ, Skelton, BW and White, AH 2006 , 'Synthesis and Structures of the Ligands 1-Methylimidazol-2-yl(pyridin-2-yl)-methanone {(py)(mim)CO} and 1-Benzylimidazol-2-yl(1-phenylaldimine)(PhN=CHbim) as their Tetracarbonylmolybdenum(0) Complexes[Mo(CO)4(L2-N,N')]' , Zeitschrift fur Anorganische und Allgemein Chemie, vol. 632, no. 5 , pp. 876-878 , doi: https://doi.org/10.1002/zaac.200500531.

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Abstract

The complexes [Mo(CO)4(L2-N,N')] [L2 = 1-methylimidazol-
2-yl(pyridin-2-yl)methanone and 1-benzylimidazol-2-yl(1-
phenylaldimine)] have been synthesized from hexacarbonylmolybdenum(0) in order to define the coordination characteristics of the bidentate nitrogen-donor ligands; the complexes exhibit distorted octahedral coordination for molybdenum(0) and cis-bidentate ligand
configurations.

Item Type: Article
Authors/Creators:Batten, MP and Canty, AJ and Cavell, KJ and Skelton, BW and White, AH
Keywords: Molybdenum; Carbonyl; Imidazole; Crystal structure
Journal or Publication Title: Zeitschrift fur Anorganische und Allgemein Chemie
ISSN: 0044-2313
DOI / ID Number: https://doi.org/10.1002/zaac.200500531
Additional Information:

"Submitted to/accepted for publication in (Zeitschrift fur Anorganische und Allgemein Chemie) (2006) WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim",

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