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Synthesis and Structure of Potassium 1-Benzylimidazole-2-carboxylate·2/3Hydrate

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Batten, MP, Canty, AJ, Cavell, KJ, Skelton, BW and White, AH 2006 , 'Synthesis and Structure of Potassium 1-Benzylimidazole-2-carboxylate·2/3Hydrate' , Zeitschrift fur Anorganische und Allgemein Chemie, vol. 632 , pp. 655-658 , doi: 10.1002/zaac.200500519.

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Abstract

The title compound, K[bimCO2]·2/3H2O (C11H19N2O2K·
2/3H2O), has been synthesized, and characterized by a single crystal X-ray study; it has the grouping [K3(bimCO2)3(OH2)2] cross-linked into a polymeric sheet in which potassium environments are diverse and unsymmetrical, containing six-coordinate and seven-coordinate geometries.

Item Type: Article
Authors/Creators:Batten, MP and Canty, AJ and Cavell, KJ and Skelton, BW and White, AH
Keywords: Potassium; Imidazole; Benzimidazole; Benzimidazole carboxylate; Bidentate Ligand; Crystal Structure
Journal or Publication Title: Zeitschrift fur Anorganische und Allgemein Chemie
DOI / ID Number: 10.1002/zaac.200500519
Additional Information:

Submitted to/accepted for publication in Zeitschrift fur Anorganische und Allgemein Chemie 2006 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim

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