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Mono(p-tolyl)platinum(II) and bis(p-tolyl)platinum(II) complexes of diethylsulfide as reagents for organoplatinum synthesis. Structures of [Pt(p-Tol)2(p-SEt2)]2 and PtCl(p-Tol)(bpy) (bpy=2,2'-bipyridine)

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Casado Lacabra, MA, Canty, AJ, Lutz, M, Patel, J, Spek, AL, Sun, H and van Koten, G 2002 , 'Mono(p-tolyl)platinum(II) and bis(p-tolyl)platinum(II) complexes of diethylsulfide as reagents for organoplatinum synthesis. Structures of [Pt(p-Tol)2(p-SEt2)]2 and PtCl(p-Tol)(bpy) (bpy=2,2'-bipyridine)' , Inorganica Chimica Acta, vol. 327, no. 1 , pp. 15-19 , doi: 10.1016/S0020-1693(01)00681-8.

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Abstract

The complex trans-PtCl(p-Tol)(SEt2)2 is obtained from the reaction of [Pt(p-Tol)2(SEt2)]2 with PtCl2(SEt2)2 and SEt2 in mole ratio 1:2:2. The mono(p-tolyl)platinum(II) and bis(p-tolyl)platinum(II) complexes of diethylsulfide react with 2,2'-bipyridine to form the complexes PtX(p-Tol)(bpy) (X=p-Tol, Cl) and are useful reagents for organoplatinum chemistry. X-ray crystal structures are presented for square planar PtCl(p-Tol)(bpy) and the centrosymmetric dimer [Pt(p-Tol)2(mu-SEt2)]2.

Item Type: Article
Authors/Creators:Casado Lacabra, MA and Canty, AJ and Lutz, M and Patel, J and Spek, AL and Sun, H and van Koten, G
Keywords: Organoplatinum; 2,2-Bipyridine; Diethylsulfide; Crystal structures
Journal or Publication Title: Inorganica Chimica Acta
ISSN: 0020-1693
DOI / ID Number: 10.1016/S0020-1693(01)00681-8
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