Please Note:

The Open Access Repository has moved to a new authentication system as of the 1st of November.

Account holders will now be able to login using their University of Tasmania credentials.
If you have trouble logging in please email us on E.Prints@utas.edu.au so we can assist you.

Public users can still access the records in this repository as normal

Open Access Repository

Entry to alkynylplatinum(IV) chemistry using hypervalent iodine(III) reagents, and the synthesis of triphenyl{4,4'-bis(tert-butyl)-2,2-bipyridine}iodoplatinum(IV)

Downloads

Downloads per month over past year

Canty, AJ and Rodemann, T (2003) Entry to alkynylplatinum(IV) chemistry using hypervalent iodine(III) reagents, and the synthesis of triphenyl{4,4'-bis(tert-butyl)-2,2-bipyridine}iodoplatinum(IV). Inorganic Chemistry Communications, 6 (11). pp. 1382-1384. ISSN 1387-7003

[img] PDF
ICC20032C_1382...pdf | Request a copy
Full text restricted
Available under University of Tasmania Standard License.

Abstract

The reaction of phenyl(alkynyl)iodine(III) triflates with diorganoplatinum(II) complexes provides a general route for the synthesis of a new class of alkynylplatinum(IV) complexes containing PtIVR2(CBCR2) groups, e.g., the 4,4'-bis(tert-butyl)-2,2'-bipyridine complexes PtIR2(CCSiMe3)(But2bpy) (R = Me, Ph); IPh2(OTf) reacts with PtPh2(But2bpy) to form the first archetypal triarylplatinum(IV) complex PtIPh3(But2bpy).

Item Type: Article
Keywords: Organoplatinum(IV); Triphenylplatinum(IV); 2,20-Bipyridine; Alkynyls; Iodonium; Iodine(III)
Journal or Publication Title: Inorganic Chemistry Communications
Page Range: pp. 1382-1384
ISSN: 1387-7003
Identification Number - DOI: 10.1016/j.inoche.2003.08.023
Additional Information:

The definitive version is available at http://www.sciencedirect.com

Date Deposited: 03 Jan 2008 23:55
Last Modified: 18 Nov 2014 03:26
Item Statistics: View statistics for this item

Actions (login required)

Item Control Page Item Control Page
TOP