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Arylation of palladium(II) and platinum(II) by diphenyliodonium triflate to form metal(IV) species, and a structural analysis of an isomer of PtIMe2Ph(bpy) (bpy = 2,2’-bipyridine)

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Bayler, A, Canty, AJ, Ryan, JH, Skelton, BW and White, AH 2000 , 'Arylation of palladium(II) and platinum(II) by diphenyliodonium triflate to form metal(IV) species, and a structural analysis of an isomer of PtIMe2Ph(bpy) (bpy = 2,2’-bipyridine)' , Inorganic Chemistry Communications, vol. 3, no. 11 , pp. 575-578 , doi: 10.1016/S1387-7003(00)00144-1.

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Abstract

The first example of aryl transfer to palladium(II) with concomitant oxidation to palladium(IV) is reported, utilising the reaction of PdMe2(bpy) (bpy = 2,2’-bipyridine)with [IPh2][O3SCF3], together with studies of an analogous platinum system and a structural analysis
of trans-PtIMe2Ph(bpy) (bpy = 2,2’-bipyridine).

Item Type: Article
Authors/Creators:Bayler, A and Canty, AJ and Ryan, JH and Skelton, BW and White, AH
Keywords: Organopalladium(IV); Organoplatinum(IV); Iodonium; Exchange reactions
Journal or Publication Title: Inorganic Chemistry Communications
ISSN: 1387-7003
DOI / ID Number: 10.1016/S1387-7003(00)00144-1
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