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Convenient synthetic routes to MePd(II), Me2Pd(II), and Me3Pd(IV) complexes. The crystal structure of the MePd(II) complex [MePd(2,2’-bipyridyl)(y-picoline)]BF4
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Byers, PK, Canty, AJ, Skelton, BW and White, AH 1987
, 'Convenient synthetic routes to MePd(II), Me2Pd(II),
and Me3Pd(IV) complexes. The crystal structure of the MePd(II) complex [MePd(2,2’-bipyridyl)(y-picoline)]BF4'
, Journal of Organometallic Chemistry, vol. 336, No. 3
, C55-C60
, doi: 10.1016/j.jorganchem.2003.12.010.
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JOMC1987,_C55.pdf | Request a copy Full text restricted Available under University of Tasmania Standard License. |
Official URL: http://dx.doi.org/10.1016/j.jorganchem.2003.12.010
Abstract
The pyridazine complex [Me2Pd(pyd)]n, stable as a solid on storage at ca. -20°C and obtained on reaction of trans-PdCl2(SMe2)2 with methyllithium and pyridazine at low temperature, is an excellent precursor for the synthesis of Me2Pd(II) and Me3Pd(IV) complexes under mild conditions, in particular for ligands sensitive to MeLi. Similarly, [MePd(SMe2)(mu-I)]2 is a suitable precursor for the synthesis of neutral and cationic MePd(II) complexes, including [MePd(2,2’-bipyridyl)(gamma-picoline)]BF4, which has been characterized by X-ray crystallography.
| Item Type: | Article |
|---|---|
| Authors/Creators: | Byers, PK and Canty, AJ and Skelton, BW and White, AH |
| Journal or Publication Title: | Journal of Organometallic Chemistry |
| ISSN: | 0022-328X |
| DOI / ID Number: | 10.1016/j.jorganchem.2003.12.010 |
| Additional Information: | The definitive version is available at http://www.sciencedirect.com/ |
| Item Statistics: | View statistics for this item |
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