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Metal-Sulphur Stretching Frequencies and Structures of Complexes of Zinc, Cadmium, and Mercury with Thiols

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Canty, AJ, Kishimoto, R, Deacon, GB and Farquharson, GJ 1976 , 'Metal-Sulphur Stretching Frequencies and Structures of Complexes of Zinc, Cadmium, and Mercury with Thiols' , Inorganica Chimica Acta, vol. 20 , pp. 161-166 , doi: 10.1016/S0020-1693(00)94110-0.

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Abstract

Assignments of vas(SMS) and vsym(SMS) for the complexes
M(SR)2 (M = Zn, Cd, Hg; R = Et, But) and Hg(SMe)2 from infrared and Raman spectroscopy are reported. Comparison of frequencies for the complex Hg(SBut)2 containing four-coordinate mercury with those of Hg(SR)2 (R = Me, Et) containing two-coordinate mercury permits assignment of a polymeric structure with linear coordination for the 1:I
complex of Hg(II) with the antidote for mercury poisoning 2,3-dimercaptopropanol (British anti-Lewisite).

Item Type: Article
Authors/Creators:Canty, AJ and Kishimoto, R and Deacon, GB and Farquharson, GJ
Journal or Publication Title: Inorganica Chimica Acta
ISSN: 0020-1693
DOI / ID Number: 10.1016/S0020-1693(00)94110-0
Additional Information:

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