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Metal-Sulphur Stretching Frequencies and Structures of Complexes of Zinc, Cadmium, and Mercury with Thiols

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Canty, AJ, Kishimoto, R, Deacon, GB and Farquharson, GJ (1976) Metal-Sulphur Stretching Frequencies and Structures of Complexes of Zinc, Cadmium, and Mercury with Thiols. Inorganica Chimica Acta, 20. pp. 161-166. ISSN 0020-1693

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Abstract

Assignments of vas(SMS) and vsym(SMS) for the complexes
M(SR)2 (M = Zn, Cd, Hg; R = Et, But) and Hg(SMe)2 from infrared and Raman spectroscopy are reported. Comparison of frequencies for the complex Hg(SBut)2 containing four-coordinate mercury with those of Hg(SR)2 (R = Me, Et) containing two-coordinate mercury permits assignment of a polymeric structure with linear coordination for the 1:I
complex of Hg(II) with the antidote for mercury poisoning 2,3-dimercaptopropanol (British anti-Lewisite).

Item Type: Article
Authors/Creators:Canty, AJ and Kishimoto, R and Deacon, GB and Farquharson, GJ
Journal or Publication Title: Inorganica Chimica Acta
Page Range: pp. 161-166
ISSN: 0020-1693
Identification Number - DOI: 10.1016/S0020-1693(00)94110-0
Additional Information:

The definitive version is available at http://www.sciencedirect.com

Date Deposited: 11 Jan 2008 00:49
Last Modified: 18 Nov 2014 03:26
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