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Structural Chemistry of the Platinum Group Metals: MC12(bpy) (M = Pd, Pt; bpy = 2,2'-Bipyridine)


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Canty, AJ, Skelton, BW, Traill, PR and White, AH 1992 , 'Structural Chemistry of the Platinum Group Metals: MC12(bpy) (M = Pd, Pt; bpy = 2,2'-Bipyridine)' , Australian Journal of Chemistry, vol. 45, no. 2 , pp. 417-422 , doi: 10.1071/CH9920417.

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A single crystal X-ray structure determination of (2,2'-bipyridine)dichloropalladium(II), isomorphous
with the 'yellow' form of the platinum(II) analogue, has been carried out. Crystals are orthorhombic, Pbca, a l8.144(5), b 15.952(5), c 7.494(2) A, Z 8, 1113 diffractometer
reflections being refined by full matrix least squares to a residual of 0.052. The planar molecules of PdCl2(bpy) are stacked into columns along the c direction, at a separation of c/2, neighbouring molecules in the stacks being related by glide planes with Pd...Pd separations
of 4.587(2) A.

Item Type: Article
Authors/Creators:Canty, AJ and Skelton, BW and Traill, PR and White, AH
Journal or Publication Title: Australian Journal of Chemistry
ISSN: 0004-9425
DOI / ID Number: 10.1071/CH9920417
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