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Synthesis of the First Organopalladium(IV) Cations, including the First X-Ray Study of Isostructural Organopalladium(IV) and Platinum(IV) Complexes, [fac-MMe3{tris(pyrazol-1-yI)methane-N,N’,N’’ }]I

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Byers, PK, Canty, AJ, Skelton, BW and White, AH 1987 , 'Synthesis of the First Organopalladium(IV) Cations, including the First X-Ray Study of Isostructural Organopalladium(IV) and Platinum(IV) Complexes, [fac-MMe3{tris(pyrazol-1-yI)methane-N,N’,N’’ }]I' , Chemical Communications , pp. 1093-1095 , doi: 10.1039/C39870001093.

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Abstract

Stable organopalladium(IV) complexes [fac-PdMe3(L)]1 (L = tridentate nitrogen donor ligand) are formed on
oxidative addition of iodomethane to PdMe2(L); the tris(pyrazo1-1-yl)methane complex is isostructural with the
platinum(IV) analogue.

Item Type: Article
Authors/Creators:Byers, PK and Canty, AJ and Skelton, BW and White, AH
Journal or Publication Title: Chemical Communications
ISSN: 1359-7345
DOI / ID Number: 10.1039/C39870001093
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