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Pi-Bonded alkene and arene complexes of silver(I): an electrospray mass spectrometric study
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Abstract
Electrospray mass spectra have been observed for a number of alkene and arene complexes of Ag(1) formed by the interaction of AgN03 and the organometallic ligand in water/methanol solution. The ES mass spectra show that almost all the alkene and arene ligands in stoichiometric excess form labile 1:2 cationic complexes with Ag(I) which are easily decomposed by collisional activation to the 1:l species. However, with a deficiency of organic ligand polymeric species are observed. The cation [Ag(cod)2]+ (cod = 1,5-cyclooctadiene) was reacted with a variety of other potential ligands, such as PPh3, AsPh3, PhSCHSPh etc. In most cases, mixed complexes [Ag(cod)(ligand)]+ were observed, and excess ligand usually produced [Ag(ligand)2]+.
Item Type: | Article |
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Authors/Creators: | Canty, AJ and Colton, R |
Journal or Publication Title: | Inorganica Chimica Acta |
ISSN: | 0020-1693 |
DOI / ID Number: | 10.1016/0020-1693(94)03861-9 |
Additional Information: | The definitive version is available at http://www.sciencedirect.com |
Item Statistics: | View statistics for this item |
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