PDF ICA1994_2C_99.pdf | Request a copy Full text restricted Available under University of Tasmania Standard License.

Abstract

Electrospray mass spectra have been observed for a number of alkene and arene complexes of Ag(1) formed by the interaction of AgN03 and the organometallic ligand in water/methanol solution. The ES mass spectra show that almost all the alkene and arene ligands in stoichiometric excess form labile 1:2 cationic complexes with Ag(I) which are easily decomposed by collisional activation to the 1:l species. However, with a deficiency of organic ligand polymeric species are observed. The cation [Ag(cod)2]+ (cod = 1,5-cyclooctadiene) was reacted with a variety of other potential ligands, such as PPh3, AsPh3, PhSCHSPh etc. In most cases, mixed complexes [Ag(cod)(ligand)]+ were observed, and excess ligand usually produced [Ag(ligand)2]+.

Item Type:	Article
Authors/Creators:	Canty, AJ and Colton, R
Journal or Publication Title:	Inorganica Chimica Acta
ISSN:	0020-1693
DOI / ID Number:	10.1016/0020-1693(94)03861-9
Additional Information:	The definitive version is available at http://www.sciencedirect.com
Item Statistics:	View statistics for this item

Actions (login required)

Item Control Page