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Platinum-Tin Bonded Complexes, Including a Structural Analysis of the Octahedral Tris(pyrazol-1-yl)borate Complex Pt(SnMe3)Me2{(pz)3BH-N,N',N"}

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Canty, AJ, Jin, H, Skelton, BW and White, AH 1999 , 'Platinum-Tin Bonded Complexes, Including a Structural Analysis of the Octahedral Tris(pyrazol-1-yl)borate Complex Pt(SnMe3)Me2{(pz)3BH-N,N',N"}' , Australian Journal of Chemistry, vol. 52, no. 5 , pp. 417-419 , doi: 10.1071/CH98166.

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Abstract

The platinum(II) complex K[PtMe2{(pz)3BH-N,N'}] reacts with SnCl2Me2 to form Pt(SnClMe2)Me2{(pz)3BH-N,N',N"} ([(pz)3BH]- =tris(pyrazol-1-yl)borate). The closely related complex Pt(SnMe3)Me2{(pz)3BH-N,N',N"} has distorted octahedral geometry for platinum with Pt-Sn 2.5727(8) A. The Pt-N distance trans to the SnMe3 group [2.237(7) A] is longer than those trans to the Me groups
[2.127(7) and 2.131(6) A], indicating for the trimethylstannyl group a trans influence which is higher
than that for the methyl group.

Item Type: Article
Authors/Creators:Canty, AJ and Jin, H and Skelton, BW and White, AH
Journal or Publication Title: Australian Journal of Chemistry
ISSN: 0004-9425
DOI / ID Number: 10.1071/CH98166
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