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Synthesis and reactivity of poly(pyrazol-1-yl)borate derivatives of cyclopalladation systems, including structural studies of Pd{2-CH2C6H4P(o-tolyl)2-C,P}{(pz)3BH-N,N'} and Pd{C6H4C5H4N-C2,N'}{(pz)3BH-N,N'}

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Canty, AJ, Hoare, JL, Skelton, BW, White, AH and van Koten, G 1998 , 'Synthesis and reactivity of poly(pyrazol-1-yl)borate derivatives of cyclopalladation systems, including structural studies of Pd{2-CH2C6H4P(o-tolyl)2-C,P}{(pz)3BH-N,N'} and Pd{C6H4C5H4N-C2,N'}{(pz)3BH-N,N'}' , Journal of Organometallic Chemistry, vol. 552, No. 1-2 , pp. 23-29 , doi: 10.1016/S0022-328X(97)00576-7.

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Abstract

The cyclopalladated complexes Pd{2-CH2C6H4P(o-tol)2}{(pz)nBH4-n} and Pd(C6H4C5H4N-C2,N'){(pz)nBH4-n} [n = 2, 3; pz =
pyrazol-1-yl] have been synthesised from the corresponding halide bridged cyclometallated dimers; the crystal structures of the complexes for which n = 3 have been determined. The complexes Pd{2-CH2C6H4P(o-tol)2}{(pz)nBH4-n} (n = 2, 3) and [Pd{2-CH2C6H4P(o-tol)2}(mu-O2CMe)]2 are unreactive towards oxidation by alkyl halides, iodobenzene and 4-bromoanisole.

Item Type: Article
Authors/Creators:Canty, AJ and Hoare, JL and Skelton, BW and White, AH and van Koten, G
Journal or Publication Title: Journal of Organometallic Chemistry
ISSN: 0022-328X
DOI / ID Number: 10.1016/S0022-328X(97)00576-7
Additional Information:

The original publication is available at www.springerlink.com

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