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The Oxidative Addition of Iodomethane to [PdMe2(bpy)] and the X-Ray Structure of the Organopalladium(IV) Product fac-[PdMe3(bpy)l] (bpy = 2,2'-bipyridyl)

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Byers, PK and Canty, AJ and Skelton, BW and White, AH (1986) The Oxidative Addition of Iodomethane to [PdMe2(bpy)] and the X-Ray Structure of the Organopalladium(IV) Product fac-[PdMe3(bpy)l] (bpy = 2,2'-bipyridyl). Journal of the Chemical Society, Chemical Communications, 23. pp. 1722-1724. ISSN 1359-7345

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Abstract

Oxidative addition of iodomethane to dimethyl(2,2'-bipyridyl)palladium(II) in acetone has resulted in isolation of the first hydrocarbylpalladium(IV) complex, fac-trimethyl(2,2'-bipyridyl)iodopalladium(IV); the complex has been structurally characterized, and reductively eliminates ethane in solution to form
methyl(2,2'-bipyridy1)iodopalladium(II).

Item Type: Article
Journal or Publication Title: Journal of the Chemical Society, Chemical Communications
Page Range: pp. 1722-1724
ISSN: 1359-7345
Identification Number - DOI: 10.1039/C39860001722
Date Deposited: 29 Jan 2008 00:51
Last Modified: 18 Nov 2014 03:27
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