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Crystal Structure of Dimethyl[tris(N-methylimidazol-2-y1)methanol-N, N ]gold(III) Nitrate

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Byers, PK, Canty, AJ, Skelton, BW and White, AH 1985 , 'Crystal Structure of Dimethyl[tris(N-methylimidazol-2-y1)methanol-N, N ]gold(III) Nitrate' , Australian Journal of Chemistry, vol. 38, no. 8 , pp. 1251-1255 , doi: 10.1071/CH9851251.

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Abstract

Crystals of dimethyl[tris(N-methylimidazol-2-yl)methanol-N,N']gold(III) nitrate are monoclinic, P21/c, a 8.217(3), b 14.010(5), c 16.800(6) A, beta 101.93(3), Z 4. The cations have the ligand coordinated as an N,N'-bidentate to cis-Me2Au(III), giving square-planar geometry for gold, together with an uncoordinated N-methylimidazol-2-yl ring above the coordination plane.

Item Type: Article
Authors/Creators:Byers, PK and Canty, AJ and Skelton, BW and White, AH
Journal or Publication Title: Australian Journal of Chemistry
ISSN: 0004-9425
DOI / ID Number: 10.1071/CH9851251
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